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Identification and dosage by HRGC of minor alcohols and esters in Brazilian sugar-cane spirit


Author(s) : W. Franco Douglas S. Lima Neto Benedito R. Cardoso Daniel B. Bezerra Cأ­cero W. Boscolo Maurأ­cio, 
Publisher : N/A
Publication Date : 2000
ISSN : N/A
Abstract : The presence of 51 volatile compounds, among alcohols and esters in Brazilian sugar-cane spirit (cachaأ§a), were investigated by high-resolution gas chromatography (HRGC). The following alcohols and esters were identified and quantified: methanol, 1,4-butanodiol, 2-phenylethyl alcohol, amyl alcohol, cetyl alcohol, cynamic alcohol, n-decanol, geraniol, isoamyl alcohol, isobutanol, menthol, n-butanol, n-dodecanol, n-propanol, n-tetradecanol, amyl propionate, ethyl acetate, ethyl benzoate, ethyl heptanoate, isoamyl valerate, methyl propionate, propyl butyrate. The average higher alcohols content (262 mg/100 mL in anhydrous alcohol a.a.) and total esters content (24 mg/100 mL a.a.) in cachaأ§as, are smaller than in other spirits. The average methanol content in cachaأ§as (6 mg/100 mL a.a.) is the same as in rum, but smaller than in wine spirit. No qualitative differences of chemical profile among cachaأ§as have been observed.,